3.3 Crystallization of Magma
The minerals that make up igneous rocks crystallize at a range of different temperatures. This explains why a cooling magma can have some crystals within it and yet remain predominantly liquid. The sequence in which minerals crystallize from a magma is known as the Bowen reaction series (Figure 3.10 and Who was Bowen).
Of the common silicate minerals, olivine normally crystallizes first, at between 1200° and 1300°C. As the temperature drops, and assuming that some silica remains in the magma, the olivine crystals react (combine) with some of the silica in the magma (see Box 3.1) to form pyroxene. As long as there is silica remaining and the rate of cooling is slow, this process continues down the discontinuous branch: olivine to pyroxene, pyroxene to amphibole, and (under the right conditions) amphibole to biotite.
At about the point where pyroxene begins to crystallize, plagioclase feldspar also begins to crystallize. At that temperature, the plagioclase is calcium-rich (anorthite) (see Figure 2.15). As the temperature drops, and providing that there is sodium left in the magma, the plagioclase that forms is a more sodium-rich variety.
Who was Bowen, and what’s a reaction series?
Norman Levi Bowen, born in Kingston Ontario, studied geology at Queen’s University and then at MIT in Boston. In 1912, he joined the Carnegie Institution in Washington, D.C., where he carried out groundbreaking experimental research into the processes of cooling magmas. Working mostly with basaltic magmas, he determined the order of crystallization of minerals as the temperature drops. The method, in brief, was to melt the rock to a magma in a specially made kiln, allow it to cool slowly to a specific temperature (allowing some minerals to form), and then quench it (cool it quickly) so that no new minerals form (only glass). The results were studied under the microscope and by chemical analysis. This was done over and over, each time allowing the magma to cool to a lower temperature before quenching.
The Bowen reaction series is one of the results of his work, and even a century later, it is an important basis for our understanding of igneous rocks. The word reaction is critical. In the discontinuous branch, olivine is typically the first mineral to form (at just below 1300°C). As the temperature continues to drop, olivine becomes unstable while pyroxene becomes stable. The early-forming olivine crystals react with silica in the remaining liquid magma and are converted into pyroxene, something like this:
Mg2SiO4 + SiO2 ——> 2MgSiO3
olivine pyroxene
This continues down the chain, as long as there is still silica left in the liquid. [image from Wikipedia: http://en.wikipedia.org/wiki/File:NormanLBowen_1909.jpg]
In cases where cooling happens relatively quickly, individual plagioclase crystals can be zoned from calcium-rich in the centre to more sodium-rich around the outside. This occurs when calcium-rich early-forming plagioclase crystals beco