Chapter 31 Radioactivity and Nuclear Physics
31.1 Nuclear Radioactivity
Summary
- Explain nuclear radiation.
- Explain the types of radiation—alpha emission, beta emission, and gamma emission.
- Explain the ionization of radiation in an atom.
- Define the range of radiation.
The discovery and study of nuclear radioactivity quickly revealed evidence of revolutionary new physics. In addition, uses for nuclear radiation also emerged quickly—for example, people such as Ernest Rutherford used it to determine the size of the nucleus and devices were painted with radon-doped paint to make them glow in the dark (see Figure 1). We therefore begin our study of nuclear physics with the discovery and basic features of nuclear radioactivity.
Discovery of Nuclear Radioactivity
In 1896, the French physicist Antoine Henri Becquerel (1852–1908) accidentally found that a uranium-rich mineral called pitchblende emits invisible, penetrating rays that can darken a photographic plate enclosed in an opaque envelope. The rays therefore carry energy; but amazingly, the pitchblende emits them continuously without any energy input. This is an apparent violation of the law of conservation of energy, one that we now understand is due to the conversion of a small amount of mass into energy, as related in Einstein’s famous equation [latex]{E=mc^2}[/latex]. It was soon evident that Becquerel’s rays originate in the nuclei of the atoms and have other unique characteristics. The emission of these rays is called nuclear radioactivity or simply radioactivity. The rays themselves are called nuclear radiation. A nucleus that spontaneously destroys part of its mass to emit radiation is said to decay (a term also used to describe the emission of radiation by atoms in excited states). A substance or object that emits nuclear radiation is said to be radioactive.
Two types of experimental evidence imply that Becquerel’s rays originate deep in the heart (or nucleus) of an atom. First, the radiation is found to be associated with certain elements, such as uranium. Radiation does not vary with chemical state—that is, uranium is radioactive whether it is in the form of an element or compound. In addition, radiation does not vary with temperature, pressure, or ionization state of the uranium atom. Since all of these factors affect electrons in an atom, the radiation cannot come from electron transitions, as atomic spectra do. The huge energy emitted during each event is the second piece of evidence that the radiation cannot be atomic. Nuclear radiation has energies of the order of [latex]{10^6 \;\text{eV}}[/latex] per event, which is much greater than the typical atomic energies (a few [latex]\text{eV}[/latex]), such as that observed in spectra and chemical reactions, and more than ten times as high as the most energetic characteristic x rays. Becquerel did not vigorously pursue his discovery for very long. In 1898, Marie Curie (1867–1934), then a graduate student married the already well-know