Converting an int into a 4 byte char array (C)

Hey, I'm looking to convert a int that is inputed by the user into 4 bytes, that I am assigning to a character array. How can this be done?

Example:

Convert a user inputs of 175 to

00000000 00000000 00000000 10101111

Issue with all of the answers so far, converting 255 should result in 0 0 0 ff although it prints out as: 0 0 0 ffffffff

unsigned int value = 255;   

buffer[0] = (value >> 24) & 0xFF;
buffer[1] = (value >> 16) & 0xFF;
buffer[2] = (value >> 8) & 0xFF;
buffer[3] = value & 0xFF;

union {
    unsigned int integer;
    unsigned char byte[4];
} temp32bitint;

temp32bitint.integer = value;
buffer[8] = temp32bitint.byte[3];
buffer[9] = temp32bitint.byte[2];
buffer[10] = temp32bitint.byte[1];
buffer[11] = temp32bitint.byte[0];

both result in 0 0 0 ffffffff instead of 0 0 0 ff

Just another example is 175 as the input prints out as 0, 0, 0, ffffffaf when it should just be 0, 0, 0, af