C# create simple xml file

You could use XDocument:

new XDocument(
    new XElement("root", 
        new XElement("someNode", "someValue")    
    )
)
.Save("foo.xml");

If the file you want to create is very big and cannot fit into memory you might use XmlWriter.

I'd recommend serialization,

public class Person
{
      public  string FirstName;
      public  string MI;
      public  string LastName;
}

static void Serialize()
{
      clsPerson p = new Person();
      p.FirstName = "Jeff";
      p.MI = "A";
      p.LastName = "Price";
      System.Xml.Serialization.XmlSerializer x = new System.Xml.Serialization.XmlSerializer(p.GetType());
      x.Serialize(System.Console.Out, p);
      System.Console.WriteLine();
      System.Console.WriteLine(" --- Press any key to continue --- ");
      System.Console.ReadKey();
}

You can further control serialization with attributes.
But if it is simple, you could use XmlDocument:

using System;
using System.Xml;

public class GenerateXml {
    private static void Main() {
        XmlDocument doc = new XmlDocument();
        XmlNode docNode = doc.CreateXmlDeclaration("1.0", "UTF-8", null);
        doc.AppendChild(docNode);

        XmlNode productsNode = doc.CreateElement("products");
        doc.AppendChild(productsNode);

        XmlNode productNode = doc.CreateElement("product");
        XmlAttribute productAttribute = doc.CreateAttribute("id");
        productAttribute.Value = "01";
        productNode.Attributes.Append(productAttribute);
        productsNode.AppendChild(productNode);

        XmlNode nameNode = doc.CreateElement("Name");
        nameNode.AppendChild(doc.CreateTextNode("Java"));
        productNode.AppendChild(nameNode);
        XmlNode priceNode = doc.CreateElement("Price");
        priceNode.AppendChild(doc.CreateTextNode("Free"));
        productNode.AppendChild(priceNode);

        // Create and add another product node.
        productNode = doc.CreateElement("product");
        productAttribute = doc.CreateAttribute("id");
        productAttribute.Value = "02";
        productNode.Attributes.Append(productAttribute);
        productsNode.AppendChild(productNode);
        nameNode = doc.CreateElement("Name